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Título: | A crystalline and free-standing silver thiocarboxylate thin-film showing high green to yellow luminescence |
Autor: | Troyano, Javier CSIC ORCID; Castillo, Óscar; Amo-Ochoa, Pilar; Fernández-Moreira, Vanesa CSIC ORCID; Gómez-García, Carlos J.; Zamora, Félix; Delgado, Salomé | Fecha de publicación: | 2016 | Editor: | Royal Society of Chemistry (UK) | Citación: | Journal of Materials Chemistry C 4(36): 8545-8551 (2016) | Resumen: | The simple direct synthesis of Cu(ii) and Ag(i) salts and thiobenzoic acid under ambient conditions allows the preparation of two bidimensional coordination polymers [M(TB)] (TB = thiobenzoate; M = Cu (1) or Ag (2)). Their electrical and luminescent properties show that these are multifunctional materials. Interestingly 1 and 2 undergo a reversible solubilization process. This unusual feature and their simple preparation allow us to prepare a crystalline and free-standing thin-film of 2, using an interfacial procedure, which shows a remarkable thermochromic luminescence. | URI: | http://hdl.handle.net/10261/154846 | DOI: | 10.1039/C6TC02401G | Identificadores: | doi: 10.1039/C6TC02401G issn: 2050-7526 |
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