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Title

A crystalline and free-standing silver thiocarboxylate thin-film showing high green to yellow luminescence

AuthorsTroyano, Javier; Castillo, Óscar; Amo-Ochoa, Pilar; Fernández-Moreira, Vanesa ; Gómez-García, Carlos J.; Zamora, Félix; Delgado, Salomé
Issue Date2016
PublisherRoyal Society of Chemistry
CitationJournal of Materials Chemistry C 4(36): 8545-8551 (2016)
AbstractThe simple direct synthesis of Cu(ii) and Ag(i) salts and thiobenzoic acid under ambient conditions allows the preparation of two bidimensional coordination polymers [M(TB)] (TB = thiobenzoate; M = Cu (1) or Ag (2)). Their electrical and luminescent properties show that these are multifunctional materials. Interestingly 1 and 2 undergo a reversible solubilization process. This unusual feature and their simple preparation allow us to prepare a crystalline and free-standing thin-film of 2, using an interfacial procedure, which shows a remarkable thermochromic luminescence.
URIhttp://hdl.handle.net/10261/154846
DOI10.1039/C6TC02401G
Identifiersdoi: 10.1039/C6TC02401G
issn: 2050-7526
Appears in Collections:(ISQCH) Artículos
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