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dc.contributor.authorBüyükyazi, Mehtapes_ES
dc.contributor.authorFischer, Thomases_ES
dc.contributor.authorPenmgei, Yues_ES
dc.contributor.authorColl, Marionaes_ES
dc.contributor.authorMathur, Sanjayes_ES
dc.date.accessioned2017-09-06T14:50:21Z-
dc.date.available2017-09-06T14:50:21Z-
dc.date.issued2017-09-01-
dc.identifier.citationDalton Transactions: 10.1039/C7DT02757E (2017)es_ES
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10261/154832-
dc.description.abstractWe present a new and efficient cobalt precursor, CoII(DMOCHCOCF3)2, to prepare Co3O4 thin films and conformal coatings. In the synthesis of this Co complex, heteroaryl moieties and CF3-groups were combined leading to high thermal stability and volatility precursor. The suitability of this precursor for ALD deposition was tested on flat silicon substrates and TiO2/C nanofibers upon process optimization. Deposition at 200ºC results in homogeneous and smooth Co3O4 thin films with a growth per cycle of 0.02 nm/cycle. Conformal coatings have been successfully obtained on TiO2/C nanofibers being thus an attractive platform for surface chemistry studies on high aspect ratio structures for future photocatalysts, sensors, supercapacitors and batteries.es_ES
dc.description.sponsorshipAuthors would like to thank University of Cologne for the financial support within the postdoc-program „Network & Exchange-NetEx“. Furthermore, they are thankful to „Fonds der chemischen Industrie“ (FCI). M.C thanks Ramón y Cajal program RYC-2013-12448. We also acknowledge financial support from the Spanish Ministry of Economy and Competitiveness, through the “Severo Ochoa” Programme for Centres of Excellence in R&D (SEV- 2015-0496), 2014-SGR-150 from the Generalitat de Catalunya, MAT2014-51778-C2-1-R and the Chinese Scholarship Council CSC fellowship (201606920073) to P.Y.es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistry (UK)es_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2015-0496es_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-51778-C2-1-Res_ES
dc.relation.isversionofPostprintes_ES
dc.rightsopenAccessen_EN
dc.titleCobalt(II)heteroarylalkenolate precursor for homogeneous Co3O4 coatings by atomic layer depositiones_ES
dc.typeartículoes_ES
dc.identifier.doi10.1039/C7DT02757E-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1039/C7DT02757Ees_ES
dc.embargo.terms2018-09-01es_ES
dc.contributor.funderUniversity of Colognees_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderGeneralitat de Catalunyaes_ES
dc.contributor.funderChina Scholarship Counciles_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100008001es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100002809es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100004543es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
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