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Title

Rhodathiaborane reaction cycles driven by C2H4 and H2: Synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]

AuthorsLuaces, Susana CSIC; Macías, Ramón CSIC ORCID; Artigas, María José CSIC; Lahoz, Fernando J. CSIC ORCID; Oro, Luis A. CSIC ORCID
Issue Date2015
PublisherRoyal Society of Chemistry (UK)
CitationDalton Transactions 44(11): 5041-5044 (2015)
AbstractNew 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by oxidation/reduction chemistry of the polyhedral boron-based clusters with ethelyne and dihydrogen.
Publisher version (URL)https://doi.org/10.1039/C4DT03677H
URIhttp://hdl.handle.net/10261/154755
DOI10.1039/C4DT03677H
Identifiersdoi: 10.1039/C4DT03677H
e-issn: 1477-9234
issn: 1477-9226
Appears in Collections:(ISQCH) Artículos




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