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Título: | Ag2Cu2O3 : The First Silver-Copper Oxide |
Autor: | Gómez-Romero, P. CSIC ORCID ; Tejada Rosales, E. M.; Palacín, M. Rosa CSIC ORCID | Palabras clave: | Oxygen Superconductors Copper Silver Solid-state structures |
Fecha de publicación: | 24-feb-1999 | Editor: | Wiley-VCH | Citación: | Angewandte Chemie International Edition 38(4): 524-525 (1999) | Resumen: | An efficient low-temperature route provides the first mixed oxide of silver and copper. Ag2Cu2O3 represents an important precedent in the search for silver-containing superconductors. It has an open structure with three-dimensional tunnels displaying square-planar CuO4 units, linerly coordinated silver ions, and vacant oxygen sites (see picture; Ag, Cu, and O are represented by white, large black, and small black spheres, respectively). The last feature allows for a rich solid-state redox chemistry. | Versión del editor: | http://dx.doi.org/10.1002/(SICI)1521-3773(19990215)38:4<524::AID-ANIE524>3.0.CO;2-F | URI: | http://hdl.handle.net/10261/15473 | DOI: | 10.1002/(SICI)1521-3773(19990215)38:4<524::AID-ANIE524>3.0.CO;2-F | ISSN: | 1433-7851 | E-ISSN: | 1521-3773 |
Aparece en las colecciones: | (ICMAB) Artículos |
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accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
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