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Polyiminopyridines based networks as supports to heterogenize iron(II) complexes. Application as efficient and selective ecofriendly catalysts

AutorMaya, Eva M. ; Verde-Sesto, Ester ; González de la Campa, José; Iglesias, Marta
Palabras claveIron
Furfural acetal
Acetalization
Glicerol
Porous polymer
Polyiminopyridines
Fecha de publicación2016
EditorChemPubSoc Europe
CitaciónChemistrySelect 1: 396-402 (2016)
ResumenA series of polyiminopyridines (PIPys) were reported and used as supports to prepare heterogenized-iron catalysts (FePIPys). The resulting PIPys exhibit moderate surface areas (SBET 200 m2 g1) and high chemical and thermal stability. The catalytic performance of FePIPys¿catalyts was studied in the acetalization of furfural and 5-hydroxymethyl furfural to yield compounds of potential interest as diesel additives. The structure of the polyiminopyridine support has great influence in the catalytic performance and recyclability; all catalysts maintained the activity and the selectivity after several cycles.
DescripciónSupporting information for this article is available on the WWW under http://dx.doi.org/10.1002/slct.201600105
Versión del editorhttp://dx.doi.org/10.1002/slct.201600105
URIhttp://hdl.handle.net/10261/153761
DOI10.1002/slct.201600105
Identificadoresdoi: 10.1002/slct.201600105
issn: 2365-6549
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