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The organic chemistry of poly(1H-pyrazol-1-yl)methanes

AutorAlkorta, Ibon ; Claramunt, Rosa M.; Díez-Barra, Enrique; Elguero, José ; Hoz, Antonio de la; López, Concepción
Palabras clavePyrazoles
Pyrazolylmethanes
Bis(1H-pyrazol-1-yl)methanes
Tris(1H-pyrazol-1-yl)methanes
Metal ligands
X-ray structures
Tetrakis(1H-pyrazol-1-yl)methanes
Fecha de publicación2017
EditorElsevier
CitaciónCoordination Chemistry Reviews 339: 153-182 (2017)
ResumenSince their first synthesis by Hückel (1937) and the first systematic exploration by Trofimenko (1970), interest in poly(1H-pyrazol-1-yl)methanes (bis, tris and tetrakis) has increased dramatically. This review focuses on the synthesis and reactivity of these ligands and contains 541 different structures and 269 references. After a brief historical introduction, the synthesis, reactivity, and nature of the coordinated metals are described along with some properties of these compounds, particularly the complete set of X-ray molecular structures. All of the formulae are represented to show the extraordinary richness of poly(1H-pyrazol-1-yl)methanes and to promote the use of the already known poly(1H-pyrazol-1-yl)methanes in coordination chemistry and the design of new ligands with the reported procedures.
Versión del editorhttp://dx.doi.org/10.1016/j.ccr.2017.03.011
URIhttp://hdl.handle.net/10261/153637
DOI10.1016/j.ccr.2017.03.011
Identificadoresdoi: 10.1016/j.ccr.2017.03.011
issn: 0010-8545
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