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Título: | High-resolution stimulated Raman spectroscopy and analysis of line positions and assignments for the ν2 and ν3 bands of 13C2H4 |
Autor: | Alkadrou, A.; Rotger, M.; Bermejo, Dionisio CSIC; Doménech, José Luis CSIC ORCID ; Boudon, V. | Palabras clave: | XTDS/SPVIEW software Tensorial formalism Stimulated Raman spectroscopy Ethylene Global analysis |
Fecha de publicación: | 18-mar-2016 | Editor: | John Wiley & Sons | Citación: | Journal of Raman Spectroscopy 47: 839-844 (2016) | Resumen: | High-resolution stimulated Raman spectra ofCH in the regions of the ν and ν Raman active modes have been recorded at two temperatures (145 and 296 K) based on the quasi continuous-wave (cw) stimulated Raman spectrometer at Instituto de Estructura de la Materia IEM-CSIC in Madrid. A tensorial formalism adapted to XY planar asymmetric tops with D symmetry (developed in Dijon) and a program suite called DTDS (now part of the XTDS/SPVIEW spectroscopic software) were proposed to analyze and calculate the high-resolution spectra. A total of 103 and 51 lines corresponding to ν and ν Raman active modes have been assigned and fitted in wavenumber with a global root mean square deviation of 0.54 × 10 and 0.36 × 10 cm, respectively. Due to the fact that the Raman scattering effect is weak, we did not perform in this contribution the line intensities analysis. © 2016 John Wiley & Sons, Ltd. | Versión del editor: | http://doi.org/10.1002/jrs.4907 | URI: | http://hdl.handle.net/10261/151451 | DOI: | 10.1002/jrs.4907 | Identificadores: | doi: 10.1002/jrs.4907 issn: 1097-4555 |
Aparece en las colecciones: | (CFMAC-IEM) Artículos |
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