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Title

High-resolution stimulated Raman spectroscopy and analysis of line positions and assignments for the ν2 and ν3 bands of 13C2H4

AuthorsAlkadrou, A.; Rotger, M.; Bermejo, Dionisio ; Doménech, José Luis ; Boudon, V.
KeywordsXTDS/SPVIEW software
Tensorial formalism
Stimulated Raman spectroscopy
Ethylene
Global analysis
Issue Date18-Mar-2016
PublisherJohn Wiley & Sons
CitationJournal of Raman Spectroscopy 47: 839-844 (2016)
AbstractHigh-resolution stimulated Raman spectra ofCH in the regions of the ν and ν Raman active modes have been recorded at two temperatures (145 and 296 K) based on the quasi continuous-wave (cw) stimulated Raman spectrometer at Instituto de Estructura de la Materia IEM-CSIC in Madrid. A tensorial formalism adapted to XY planar asymmetric tops with D symmetry (developed in Dijon) and a program suite called DTDS (now part of the XTDS/SPVIEW spectroscopic software) were proposed to analyze and calculate the high-resolution spectra. A total of 103 and 51 lines corresponding to ν and ν Raman active modes have been assigned and fitted in wavenumber with a global root mean square deviation of 0.54 × 10 and 0.36 × 10 cm, respectively. Due to the fact that the Raman scattering effect is weak, we did not perform in this contribution the line intensities analysis. © 2016 John Wiley & Sons, Ltd.
Publisher version (URL)http://doi.org/10.1002/jrs.4907
URIhttp://hdl.handle.net/10261/151451
DOI10.1002/jrs.4907
Identifiersdoi: 10.1002/jrs.4907
issn: 1097-4555
Appears in Collections:(CFMAC-IEM) Artículos
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