English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/151394
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Exportar a otros formatos:

Title

NMR signal enhancement > 50000 times in Fast Dissolution Dynamic Nuclear Polarization

AuthorsPinto, Luiz Fernando; Marín-Montesinos, Ildefonso; Lloveras, Vega ; Muñoz Gómez, José L ; Pons, Miquel; Veciana, Jaume ; Vidal Gancedo, José
KeywordsSolid-state NMR
Trityl-nitroxide biradicals
C-13 magnetic-resonance
Broadened ESR line
Irradiated polyethylenes
Polarizing agent
Spectroscopy
Radicals
BDPA
DNP
Issue Date4-Apr-2017
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 53(26): 3757-3760 (2017)
AbstractHerein, we report the synthesis and the study of a novel mixed biradical with BDPA and TEMPO radical units that are covalently bound by an ester group (BDPAesterTEMPO) as a polarizing agent for fast dissolution DNP. The biradical exhibits an extremely high DNP NMR enhancement of >50[thin space (1/6-em)]000 times, which constitutes one of the largest signal enhancements observed so far, to the best of our knowledge.
Publisher version (URL)http://dx.doi.org/10.1039/C7CC00635G
URIhttp://hdl.handle.net/10261/151394
DOI10.1039/C7CC00635G
ISSN1359-7345
Appears in Collections:(ICMAB) Artículos
Files in This Item:
File Description SizeFormat 
Pinto_ChemComm_2017_postprint.pdf389,31 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.