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Title

Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation

AuthorsAlbalad, Jorge ; Aríñez-Soriano, Javier; Vidal Gancedo, José ; Lloveras, Vega ; Juanhuix, Jordi; Imaz, Inhar ; Aliaga Alcalde, Nuria ; Maspoch, Daniel
KeywordsMetal-organic frameworks
MOFs
Adsorption
Conversion
Ligands
Design
Issue Date21-Oct-2016
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 52(91): 13397-13400 (2016)
AbstractHerein we report a water-induced single-crystal to single-crystal transformation that involves the formation of hetero-bimetallic paddlewheel clusters in coordination polymers. Through this transformation, which involves the cleavage and formation of different coordination bonds, two different Cu(II)-Zn(II) and Cu(II)-Ni(II) paddle-wheel units exhibiting a 1 : 1 metal ratio were created.
Publisher version (URL)http://dx.doi.org/10.1039/C6CC07653J
URIhttp://hdl.handle.net/10261/150350
DOI10.1039/C6CC07653J
ISSN1359-7345
Appears in Collections:(ICMAB) Artículos
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