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Title

The organocatalytic desymmetrization of meso-ferrocene anhydride

AuthorsValderas, Carolina; Casarrubios, Luis; Torre, María C. de la ; Sierra, Miguel A.
KeywordsDesymmetrization
Organocatalysis
Squaramides
Chiral ligands
meso-Ferrocenes
Issue Date2017
PublisherElsevier
CitationTetrahedron Letters 58: 326-328 (2017)
AbstractA new and unique organocatalytic process for the desymmetrization of meso ferrocene anhydride has been developed. After optimization with a series of quinine, quinidine and squaramide ligands, the method was effective with a 60% isolated yield and 98% ee.
DescriptionSupplementary data associated with this article can be found, in the online version, at http://dx.doi.org/10.1016/j.tetlet.2016.12. 025.
Publisher version (URL)http://dx.doi.org/10.1016/j.tetlet.2016.12.025
URIhttp://hdl.handle.net/10261/148919
DOI10.1016/j.tetlet.2016.12.025
Identifiersdoi: 10.1016/j.tetlet.2016.12.025
issn: 1873-3581
Appears in Collections:(IQOG) Artículos
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