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http://hdl.handle.net/10261/148774
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Li, Yuan | es_ES |
dc.contributor.author | Franco, Carlos | es_ES |
dc.contributor.author | Crivillers, Núria | es_ES |
dc.contributor.author | Mas Torrent, Marta | es_ES |
dc.contributor.author | Liang, Cao | es_ES |
dc.contributor.author | Suchand Sangeeth, C.S. | es_ES |
dc.contributor.author | Rovira, Concepció | es_ES |
dc.contributor.author | Veciana, Jaume | es_ES |
dc.contributor.author | Nijhuis, Christian A. | es_ES |
dc.date.accessioned | 2017-04-24T13:42:07Z | - |
dc.date.available | 2017-04-24T13:42:07Z | - |
dc.date.issued | 2016-07-26 | - |
dc.identifier.citation | Nature Communications 7: 12066 (2016) | es_ES |
dc.identifier.issn | 2041-1723 | - |
dc.identifier.uri | http://hdl.handle.net/10261/148774 | - |
dc.description.abstract | The energy-level alignment of molecular transistors can be controlled by external gating to move molecular orbitals with respect to the Fermi levels of the source and drain electrodes. Two-terminal molecular tunnelling junctions, however, lack a gate electrode and suffer from Fermi-level pinning, making it difficult to control the energy-level alignment of the system. Here we report an enhancement of 2 orders of magnitude of the tunnelling current in a two-terminal junction via chemical molecular orbital control, changing chemically the molecular component between a stable radical and its non-radical form without altering the supramolecular structure of the junction. Our findings demonstrate that the energy-level alignment in self-assembled monolayer-based junctions can be regulated by purely chemical modifications, which seems an attractive alternative to control the electrical properties of two-terminal junctions. | es_ES |
dc.description.sponsorship | The National Research Foundation, Prime Minister’s Office, Singapore under its Medium sized centre programme, and for the NRF fellowship to C.A.N., award No. NRF-RF 2010-03, is kindly acknowledged for supporting this research. C.F., N.C., M.M.-T., C.R. and J.V. acknowledge the CSIC funded i-LINK0841project, the EU FP7 program through ACMOL collaborative project (GA n 618082), ERC StG 2012-306826 e-GAMES, CIG (PCIG10-GA-2011-303989) and ITN iSwitch (GA no. 642196), the financial support from the DGI (Spain) (CTQ2013-40480-R), Spanish Ministry of Economy and Competitiveness, through the ‘Severo Ochoa’ Programme for Centres of Excellence in R&D (SEV-2015-0496), the Generalitat de Catalunya (2014SGR-17) and the Networking Research Center of Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN); N.C. acknowledges the RyC program; C.F. is enroled in the Materials Science PhD program of UAB. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Nature Publishing Group | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/618082 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/306826 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/303989 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/642196 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2013-40480-R | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2015-0496 | es_ES |
dc.relation.isversionof | Publisher's version | es_ES |
dc.rights | openAccess | es_ES |
dc.subject | Electronic properties and materials | es_ES |
dc.subject | Physical chemistry | es_ES |
dc.subject | Superconductors | es_ES |
dc.title | Chemical control over the energy-level alignment in a two-terminal junction | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1038/ncomms12066 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1038/ncomms12066 | es_ES |
dc.rights.license | https://creativecommons.org/licenses/by/4.0/ | es_ES |
dc.contributor.funder | National Research Foundation Singapore | es_ES |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | European Research Council | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | Generalitat de Catalunya | es_ES |
dc.contributor.funder | Centro de Investigación Biomédica en Red Bioingeniería, Biomateriales y Nanomedicina (España) | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100001381 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000781 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100002809 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100005053 | es_ES |
dc.identifier.pmid | 27456200 | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.languageiso639-1 | en | - |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.openairetype | artículo | - |
Aparece en las colecciones: | (ICMAB) Artículos |
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Li_NatComm_2016_editorial.pdf | Artículo principal | 856,39 kB | Adobe PDF | Visualizar/Abrir |
Li_NatComm_2016_suppl_editorial.pdf | Información suplementaria | 2,89 MB | Adobe PDF | Visualizar/Abrir |
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