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Título: | Methyl Complexes of the Transition Metals |
Autor: | Campos, Jesús CSIC ORCID CVN; López-Serrano, Joaquín CSIC ORCID CVN; Peloso, Riccardo CSIC ORCID; Carmona, Ernesto CSIC ORCID | Fecha de publicación: | 2016 | Editor: | John Wiley & Sons | Citación: | Chemistry - A European Journal 22: 6432- 6457 (2016) | Resumen: | Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, that is, based essentially on carbon, with molecular inorganic chemistry, especially with coordination compounds. Transition-metal methyl complexes probably represent the simplest and most fundamental way to view how these two major areas of chemistry combine and merge into novel species with intriguing features in terms of reactivity, structure, and bonding. Citing more than 500 bibliographic references, this review aims to offer a concise view of recent advances in the field of transition-metal complexes containing M-CH fragments. Taking into account the impressive amount of data that are continuously provided by organometallic chemists in this area, this review is mainly focused on results of the last five years. After a panoramic overview on M-CH compounds of Groups 3 to 11, which includes the most recent landmark findings in this area, two further sections are dedicated to methyl-bridged complexes and reactivity. | URI: | http://hdl.handle.net/10261/148672 | DOI: | 10.1002/chem.201504483 | Identificadores: | doi: 10.1002/chem.201504483 issn: 1521-3765 |
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Manuscript_revised - Copia.pdf | 2,24 MB | Adobe PDF | Visualizar/Abrir |
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