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All-carbon electrode molecular electronic devices based on Langmuir–Blodgett monolayers

AuthorsSangiao, S.; Martín, Santiago; González-Orive, Alejandro; Magen, Cesar; Low, Paul J.; Teresa, José María de; Cea, Pilar
KeywordsMolecular electronics
Issue Date2017
CitationSmall 13(7): 1603207 (2017)
AbstractNascent molecular electronic devices, based on monolayer Langmuir–Blodgett films sandwiched between two carbonaceous electrodes, have been prepared. Tightly packed monolayers of 4-((4-((4-ethynylphenyl)ethynyl)phenyl)ethynyl)benzoic acid are deposited onto a highly oriented pyrolytic graphite electrode. An amorphous carbon top contact electrode is formed on top of the monolayer from a naphthalene precursor using the focused electron beam induced deposition technique. This allows the deposition of a carbon top-contact electrode with well-defined shape, thickness, and precise positioning on the film with nm resolution. These results represent a substantial step toward the realization of integrated molecular electronic devices based on monolayers and carbon electrodes.
Identifiersdoi: 10.1002/smll.201603207
e-issn: 1613-6829
issn: 1613-6810
Appears in Collections:(ICMA) Artículos
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