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A symmetric, triply interlaced 3-D anionic MOF that exhibits both magnetic order and SMM behaviour

AuthorsCampo, Javier ; Falvello, Larry R.; Forcén-Vázquez, E.; Sáenz de Pipaón, C.; Palacio, Fernando; Tomás, Milagros
Issue Date2016
PublisherRoyal Society of Chemistry (UK)
CitationDalton Transactions 45(42): 16764-16768 (2016)
AbstractA newly prepared 3-D polymer of cobalt citrate cubanes bridged by high-spin Co(ii) centres displays both single-molecule magnet (SMM) behaviour and magnetic ordering. Triple interpenetration of the 3-D diamondoid polymers yields a crystalline solid with channels that host cations and free water molecules, with the SMM behaviour of the CoO cores preserved. The octahedrally coordinated Co(ii) bridges are implicated in the onset of magnetic order at an experimentally accessible temperature.
Publisher version (URL)https://doi.org/10.1039/c6dt02652d
Identifiersdoi: 10.1039/c6dt02652d
e-issn: 1477-9234
issn: 1477-9226
Appears in Collections:(ISQCH) Artículos
(ICMA) Artículos
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