English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/148271
COMPARTIR / IMPACTO:
Estadísticas
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Título

New polycatenar Schiff bases derived from 1,3,4-thiadiazole: synthesis, mesomorphism and luminescence behaviour

AutorElgueta, Elizabeth Y.; Parra, M. L.; Barberá, Joaquín; Vergara, Jorge; Dahrouch, Mohamed; Díaz, Enzo W.
Palabras clavePolycatenar
Schiff bases
Hexagonal columnar mesophase
134-thiadiazole
Fecha de publicación2016
EditorTaylor & Francis
CitaciónLiquid Crystals 43(11): 1649-1658 (2016)
ResumenTwo new series of columnar liquid crystal materials based on tetra- and hexacatenar Schiff bases were synthesised by reaction of 4-aminophenyl-1,3,4-thiadiazole derivatives with terephthalaldehyde (series 2a–f) and with 2,5-thiophenedicarbaldehyde (series 3a–f). The mesomorphic properties of these compounds were studied by differential scanning calorimetry (DSC), polarised optical microscopy (POM) and X-ray diffraction (XRD). The mesomorphic behaviour was found to be dependent on the nature of the central ring (benzene in series 2a–f, thiophene in series 3a–f), on length and on number of alkoxy chains. Both tetra- and hexacatenar compounds in series 2a–f display an enantiotropic hexagonal columnar phase. Whereas, in the case of the series 3, only the tetracatenar Schiff bases (3a, 3c and 3e) display enantiotropic hexagonal columnar mesomorphism, hexacatenar Schiff bases (3b, 3d and 3f) do not show mesomorphic properties. Photophysical studies were realised in solution and in solid state. Also, a thermogravimetric analysis was performed. A fibre obtained from compound 3b was analysed by POM showing that the mesophase is maintained in the fibre.
URIhttp://hdl.handle.net/10261/148271
DOI10.1080/02678292.2016.1193907
Identificadoresdoi: 10.1080/02678292.2016.1193907
e-issn: 1366-5855
issn: 0267-8292
Aparece en las colecciones: (ICMA) Artículos
Ficheros en este ítem:
Fichero Descripción Tamaño Formato  
accesoRestringido.pdf15,38 kBAdobe PDFVista previa
Visualizar/Abrir
Mostrar el registro completo
 


NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.