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Título

Reaction of Methyl Gibberellate with Triphenylphosphine and Carbon Tetrachloride

AutorDuri, James Z.; Fraga, Braulio M. ; Hanson, James R.
Fecha de publicación1981
EditorRoyal Society of Chemistry (Great Britain)
CitaciónJournal of the Chemical Society - Perkin Transactions I 1981: 3016-3019 (1981)
ResumenTreatment of methyl gibberellate and its 3-epimer with triphenylphosphine and carbon tetrachloride containing acetone or pyridine, gave the 1β-chloro- and 1β,13-dichloro-Δ2-derivatives respectively as the major products. The 3-chloro-compounds were obtained as minor products. The 1-bromo-compounds were obtained with carbon tetrabromide. The structures of these compounds were established by location of the label in the products from methyl 3-epi-[3β-2H]gibberellate.
Descripción4 pages, 1 table, 1 scheme.
Versión del editorhttp://dx.doi.org/10.1039/P19810003016
URIhttp://hdl.handle.net/10261/14795
DOI10.1039/P19810003016
ISSN1472-7781
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