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‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

AuthorsRichardson, Paul; Alexandropoulos, Dimitris I.; Cunha-Silva, Luís; Lorusso, Giulia; Evangelisti, Marco CSIC ORCID ; Tang, Jinkui; Stamatatos, Theocharis C.
Issue Date2015
PublisherRoyal Society of Chemistry (UK)
CitationInorganic Chemistry Frontiers 2(10): 945-948 (2015)
AbstractA new family of isomorphous [Cu4Ln] clusters (LnIII = Gd, Tb, Dy) with a ‘propeller’-like topology was obtained from the use of naphthalene-2,3-diol in CuII/LnIII chemistry; all complexes are ferromagnetically-coupled and display either magnetocaloric properties or SMM behavior depending on the central Ln ion.
Publisher version (URL)https://doi.org/10.1039/c5qi00146c
Identifiersdoi: 10.1039/c5qi00146c
e-issn: 2052-1553
Appears in Collections:(ICMA) Artículos
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