English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/147227
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Exportar a otros formatos:


Entropy-driven homochiral self-sorting of a dynamic library

AuthorsAtcher, Joan; Bujons, Jordi; Alfonso, Ignacio
Issue Date2017
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications
AbstractA dynamic mixture of stereoisomeric macrocycles derived from glutamic acid displayed a homochiral self-selection when increasing the acetonitrile content of the aqueous mixed medium. The homochiral self-sorting required the anionic form of the side chains and increased at higher temperature, implying an entropic origin. Conformational analysis (NMR and MD simulations) allowed us to explain the observed behaviour. The results show that entropy can play a role in the homochiral self-sorting in adaptive bio-inspired chemical systems.
Publisher version (URL)10.1039/C7CC01153A
Appears in Collections:(IQAC) Artículos
Files in This Item:
File Description SizeFormat 
ChemCommun_Homochir_Just_Accepted-1.pdf565,38 kBAdobe PDFThumbnail
Show full item record
Review this work

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.