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Scattering study of the Ne + NeH^+(v0 = 0, j0 = 0) -> NeH^+ + Ne reaction on an ab initio based analytical potential energy surface

AuthorsKoner, Debasish; Barrios, Lizandra; González-Lezana, Tomás ; Panda, Aditya N.
Issue Date19-Jan-2016
PublisherAmerican Institute of Physics
CitationJournal of Chemical Physics 144: 034303 (2016)
AbstractInitial state selected dynamics of the Ne + NeH+(v0 = 0, j0 = 0) ¿ NeH+ + Ne reaction is investigated by quantum and statistical quantum mechanical (SQM) methods on the ground electronic state. The three-body ab initio energies on a set of suitably chosen grid points have been computed at CCSD(T)/aug-cc-PVQZ level and analytically fitted. The fitting of the diatomic potentials, computed at the same level of theory, is performed by spline interpolation. A collinear [NeHNe]+ structure lying 0.72 eV below the Ne + NeH+ asymptote is found to be the most stable geometry for this system. Energies of low lying vibrational states have been computed for this stable complex. Reaction probabilities obtained from quantum calculations exhibit dense oscillatory structures, particularly in the low energy region and these get partially washed out in the integral cross section results. SQM predictions are devoid of oscillatory structures and remain close to 0.5 after the rise at the threshold thus giving a crude average description of the quantum probabilities. Statistical cross sections and rate constants are nevertheless in sufficiently good agreement with the quantum results to suggest an important role of a complex-forming dynamics for the title reaction. ©2016 AIP Publishing
Description11 págs.; 7 figs.; 4 tabs.
Publisher version (URL)http://doi.org/10.1063/1.4939952
Identifiersdoi: 10.1063/1.4939952
issn: 0021-9606
Appears in Collections:(CFMAC-IFF) Artículos
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