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A first cyclodextrin-transition metal coordination polymer

AuthorsXu, Heng ; Rodríguez-Hermida, Sabina ; Pérez-Carvajal, Javier ; Juanhuix, Jordi; Imaz, Inhar ; Maspoch, Daniel
Issue Date2016
PublisherAmerican Chemical Society
CitationCrystal Growth and Design 16(10): 5598-5602 (2016)
AbstractThe synthesis, X-ray crystallographic structure, and water uptake measurements of the first coordination polymer made of a cyclodextrin and a transition metal ion (in this case, Cu) are shown. This coordination polymer is made by connecting paddle-wheel Cu units through a γ-cyclodextrin functionalized with eight carboxylate groups, is stable in water, and shows selective water-induced reversible structural transformations.
Publisher version (URL)https://doi.org/10.1021/acs.cgd.6b01115
Identifiersdoi: 10.1021/acs.cgd.6b01115
e-issn: 1528-7505
issn: 1528-7483
Appears in Collections:(CIN2) Artículos
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