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Freezing the nonclassical crystal growth of a coordination polymer using controlled dynamic gradients

AuthorsRubio-Martínez, Marta; Imaz, Inhar ; Domingo, Neus ; Carbonell, Carlos ; Amabilino, David B. ; Maspoch, Daniel ; Puigmartí Luis, Josep
KeywordsCrystal growth
Out-of-equilibrium structures
Coordination polymers
Issue Date2016
PublisherJohn Wiley & Sons
CitationAdvanced Materials 28(37): 8150-8155 (2016)
AbstractA methodology that can be efficiently used to synthesize, isolate, and study out-of-equilibrium crystal structures employing controlled and diffusion-limited microfluidic environments is demonstrated. Unlike studies conducted with conventional mixing procedures in a flask, it is proven experimentally and with numerical simulations that microfluidic technologies can undoubtedly fine-tune reaction times and reagents concentration profiles; factors that enable out-of-equilibrium crystal forms to be obtained.
Identifiersdoi: 10.1002/adma.201506462
e-issn: 1521-4095
issn: 0935-9648
Appears in Collections:(CIN2) Artículos
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