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Title

Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption

AuthorsAríñez-Soriano, Javier; Albalad, Jorge ; Vila-Parrondo, Christian; Pérez-Carvajal, Javier ; Rodríguez-Hermida, Sabina ; Cabeza, Aurelio; Juanhuix, Jordi; Imaz, Inhar ; Maspoch, Daniel
Issue Date2016
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 52(45): 7229-7232 (2016)
AbstractHerein we report a study on water adsorption/desorption-triggered single-crystal to single-crystal transformations in a MOF, by single-crystal and humidity-controlled powder X-ray diffraction and water-sorption measurements. We identified a gate-opening effect at a relative humidity of 85% upon water adsorption, and a gate-closure effect at a relative humidity of 55 to 77% upon water desorption. This reversible breathing effect between the "open" and the "closed" structures of the MOF involves the cleavage and formation of several coordination bonds.
URIhttp://hdl.handle.net/10261/143182
DOIhttp://dx.doi.org/10.1039/c6cc02908f
Identifiersdoi: 10.1039/c6cc02908f
e-issn: 1364-548X
issn: 1359-7345
Appears in Collections:(CIN2) Artículos
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