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Nucleophilic additions to coordinated 1,10-phenanthroline: intramolecular, intermolecular, reversible, and irreversible

AuthorsArévalo, Rebeca; Menéndez, M. Isabel; López, Ramón; Merino, Isabel; Riera, Lucía ; Pérez, Julio
KeywordsN ligands
Nucleophilic addition
Phenanthroline complexes
Pyridine dearomatization
Rhenium carbonyls
Issue Date2016
CitationChemistry - A European Journal 22(50): 17972-17975 (2016)
AbstractKN(SiMe3)2 reacts with [Re(CO)3(phen)(PMe3)]OTf via reversible addition to the phen ligand and irreversible deprotonation of the PMe3 ligand followed by intramolecular attack to phen by the deprotonated phosphane, whereas MeLi irreversibly adds to phen. The addition of MeLi has been shown to be intermolecular, unlike previously known nucleophilic additions to pyridines.
Publisher version (URL)https://doi.org/10.1002/chem.201604438
Appears in Collections:(CINN) Artículos
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