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Activation of aromatic C−C bonds of 2,2’-bipyridine ligands

AuthorsFombona, Sergio; Espinal Viguri, Maialen; Huertos, Miguel A.; Díaz, Jesús; López, Ramón; Menéndez, M. Isabel; Pérez, Julio ; Riera, Lucía
Pyridine activation
C−C coupling
Density functional calculations
Issue Date2016
CitationChemistry - A European Journal 22(48): 17160-17164 (2016)
Abstract4,4’-Disubstituted-2,2′-bipyridine ligands coordinated to Mo and Re cationic fragments become dearomatized by an intramolecular nucleophilic attack from a deprotonated N-alkylimidazole ligand in cis disposition. The subsequent protonation of these neutral complexes takes place on a pyridine carbon atom rather than at nitrogen, weakening an aromatic C−C bond and affording a dihydropyridyl moiety. Computational calculations allowed for the rationalization of the formation of the experimentally obtained products over other plausible alternatives.
Publisher version (URL)https://doi.org/10.1002/chem.201603433
Identifiersdoi: 10.1002/chem.201603433
e-issn: 1521-3765
issn: 0947-6539
Appears in Collections:(CINN) Artículos
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