English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/141334
Share/Impact:
Statistics
logo share SHARE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
DC FieldValueLanguage
dc.contributor.authorArévalo, Rebecaes_ES
dc.contributor.authorEspinal Viguri, Maialenes_ES
dc.contributor.authorHuertos, Miguel A.es_ES
dc.contributor.authorPérez, Julioes_ES
dc.contributor.authorRiera, Lucíaes_ES
dc.date.accessioned2016-12-13T08:38:01Z-
dc.date.available2016-12-13T08:38:01Z-
dc.date.issued2016-
dc.identifier.citationAdvances in Organometallic Chemistry 65: 47-114 (2016)es_ES
dc.identifier.isbn978-0-12-804710-1-
dc.identifier.issn0065-3055-
dc.identifier.urihttp://hdl.handle.net/10261/141334-
dc.descriptionChapter Two.-
dc.description.abstract2,2′-Bipyridine (bipy) and 1,10-phenanthroline (phen), employed for a long time in all areas of coordination chemistry, are archetypical auxiliary ligands that stabilize metal fragments but are not themselves the site of the reactivity. Several examples of dearomatization of one of the pyridine rings of coordinated bipy and phen are discussed, including one example of ring opening. The highly reactive species resulting from deprotonation of coordinated N-alkylimidazoles can result, besides of the mentioned dearomatization, in other intramolecular C–C coupling reactions involving monodentate pyridines, other N-alkylimidazoles, imine, nitrile, isonitrile, and carbonyl ligands. In some examples, the products of these couplings, and of those between two pyridines, can be oxidatively rearomatized, affording pyridylimidazoles and bipyridines. Similar reactions leading to C–C couplings have been demonstrated for deprotonation of dimethylsulfide and methylphosphane ligands. In some instances, the deprotonation of coordinated N-alkylimidazoles produces complexes with rare N-alkylimidazol-2-yl ligands. The protonation or alkylation of the nonsubstituted nitrogen of the latter affords coordinated N-heterocyclic carbenes.es_ES
dc.description.sponsorshipThe authors gratefully acknowledge funding from Ministerio de Economía y Competitividad and FEDER (grants CTQ2012-37379-C02-01 and CTQ2012-37379-C02-02, and FPI graduate studentships to M.E.V. and M.A.H.) and Principado de Asturias (grant FC-15-GRUPIN14-103, administered by FICYT) and Ministerio de Educación Cultura y Deporte (FPU graduate studentship to R.A.).es_ES
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relation.ispartofseriesAdvances in Organometallic Chemistry-
dc.relation.isversionofPostprintes_ES
dc.rightsopenAccessen_EN
dc.subjectDearomatizationes_ES
dc.subjectC–C couplinges_ES
dc.subjectImidazole-2-yl ligandes_ES
dc.subjectNitrogen-heterocyclic carbenees_ES
dc.subjectModular synthesises_ES
dc.subjectNucleophilic attack to pyridinees_ES
dc.subjectDihydropyridine ligandses_ES
dc.subjectReactivity of coordinated bipy and phenes_ES
dc.titleDearomatization of transition metal-coordinated N-heterocyclic ligands and related chemistryes_ES
dc.typecapítulo de libroes_ES
dc.identifier.doi10.1016/bs.adomc.2016.03.002-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1016/bs.adomc.2016.03.002es_ES
dc.embargo.terms2018-05-25es_ES
dc.contributor.funderMinisterio de Educación, Cultura y Deporte (España)es_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderPrincipado de Asturiases_ES
dc.contributor.funderFundación para el Fomento en Asturias de la Investigación Científica Aplicada y la Tecnologíaes_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003176es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100008430es_ES
Appears in Collections:(CINN) Libros y partes de libros
Files in This Item:
File Description SizeFormat 
AdvOmCap2.pdf2,29 MBAdobe PDFThumbnail
View/Open
Show simple item record
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.