English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/141334
Share/Impact:
Statistics
logo share SHARE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Title

Dearomatization of transition metal-coordinated N-heterocyclic ligands and related chemistry

AuthorsArévalo, Rebeca; Espinal Viguri, Maialen; Huertos, Miguel A.; Pérez, Julio ; Riera, Lucía
KeywordsDearomatization
C–C coupling
Imidazole-2-yl ligand
Nitrogen-heterocyclic carbene
Modular synthesis
Nucleophilic attack to pyridine
Dihydropyridine ligands
Reactivity of coordinated bipy and phen
Issue Date2016
PublisherElsevier
CitationAdvances in Organometallic Chemistry 65: 47-114 (2016)
SeriesAdvances in Organometallic Chemistry
Abstract2,2′-Bipyridine (bipy) and 1,10-phenanthroline (phen), employed for a long time in all areas of coordination chemistry, are archetypical auxiliary ligands that stabilize metal fragments but are not themselves the site of the reactivity. Several examples of dearomatization of one of the pyridine rings of coordinated bipy and phen are discussed, including one example of ring opening. The highly reactive species resulting from deprotonation of coordinated N-alkylimidazoles can result, besides of the mentioned dearomatization, in other intramolecular C–C coupling reactions involving monodentate pyridines, other N-alkylimidazoles, imine, nitrile, isonitrile, and carbonyl ligands. In some examples, the products of these couplings, and of those between two pyridines, can be oxidatively rearomatized, affording pyridylimidazoles and bipyridines. Similar reactions leading to C–C couplings have been demonstrated for deprotonation of dimethylsulfide and methylphosphane ligands. In some instances, the deprotonation of coordinated N-alkylimidazoles produces complexes with rare N-alkylimidazol-2-yl ligands. The protonation or alkylation of the nonsubstituted nitrogen of the latter affords coordinated N-heterocyclic carbenes.
DescriptionChapter Two.
Publisher version (URL)http://dx.doi.org/10.1016/bs.adomc.2016.03.002
URIhttp://hdl.handle.net/10261/141334
DOI10.1016/bs.adomc.2016.03.002
ISBN978-0-12-804710-1
ISSN0065-3055
Appears in Collections:(CINN) Libros y partes de libros
Files in This Item:
File Description SizeFormat 
AdvOmCap2.pdf2,29 MBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.