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Title

19,19’-diacyloxy signature: an atypical level of structural evolution in carotenoid pigments

AuthorsGavalás, Antonio; Álvarez, Susana; Riobó, Pilar ; Rodríguez, Francisco; Garrido, J. L. ; Vaz, Belén
Issue Date2016
PublisherAmerican Chemical Society
CitationOrganic Letters 18(18): 4642-4645 (2016)
AbstractWe report the isolation from the green dinoflagellate Lepidodinium chlorophorum and structural characterization of a new carotenoid termed lepidoxanthin 1, determined to be (3S,5R,6S,3´R,6´R)-5,6-epoxy-19-(2-decenoyloxy)-19´-acetoxy-4´,5´- didehydro-5,6,5´,6´-tetrahydro-β,ε-carotene-3,3´-diol. Its until now unidentified 19,19´-diacyloxy substitution constitutes a chemical signature that can aid to unravel the evolutionary course of this unicellular algae based on the proposed biosynthethic pathway from lutein.
Description5 páginas, 4 figuras
Publisher version (URL)http://dx.doi.org/10.1021/acs.orglett.6b02272
URIhttp://hdl.handle.net/10261/138019
DOI10.1021/acs.orglett.6b02272
ISSN1523-7060
E-ISSN1523-7052
Appears in Collections:(IIM) Artículos
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