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Laser treatment of nanoparticulated metal thin films for ceramic tile decoration

AutorRico, Víctor J. ; Lahoz, Ruth; Rey-García, F.; Yubero, Francisco ; Espinós, J.P. ; Fuente, Germán F. de la; González-Elipe, Agustín R.
Fecha de publicación2016
EditorAmerican Chemical Society
CitaciónACS Applied Materials and Interfaces 8(37): 24880−24886 (2016)
ResumenThis paper presents a new method for the fabrication of metal-like decorative layers on glazed ceramic tiles. It consists of the laser treatment of copper thin films prepared by electron beam evaporation at glancing angles. A thin film of discontinuous copper nanoparticles was electron beam evaporated in an oblique angle configuration onto ceramic tiles and an ample palette of colors obtained by laser treatment both in air and in vacuum. Scanning electron microscopy (SEM and FESEM) along with UV-vis-NIR spectroscopy and time of flight secondary ion mass spectrometry (TOF-SIMS) analysis were used to characterize the differently colored layers. Based on these analyses, color development has been accounted for by a simple model considering surface melting phenomena and different microstructural and chemical transformations of the outmost surface layers of samples.
Versión del editorhttp://dx.doi.org/10.1021/acsami.6b07469
URIhttp://hdl.handle.net/10261/137861
DOI10.1021/acsami.6b07469
ISSN1944-8244
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