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Exploring a novel preparation method of 1D metal organic frameworks based on supercritical CO2

AuthorsLópez Periago, Ana M. ; Vallcorba, Oriol ; Frontera, C.; Domingo, C.; Ayllón, José A.
Issue Date9-Mar-2015
PublisherRoyal Society of Chemistry (UK)
CitationDalton Transactions 44: 7548-7553 (2015)
AbstractThe preparation of copper(II) one-dimensional MOFs using an eco-efficient method is reported here. This method is based exclusively on using supercritical CO<inf>2</inf> as a solvent, without the addition of any other additive or co-solvent. Neutral acetylacetonate copper complexes and two linear linkers, namely, the bidentate 4,4¿-bipyridine and 4,4¿-trimethylenedipyridine molecules, were reacted under compressed CO<inf>2</inf> at 60 °C and 20 MPa for periods of 4 or 24 h. The success achieved in the synthesis of the different studied 1D-MOFs was related to the solubility of the reagents in supercritical CO<inf>2</inf>. The reaction yield of the synthesized coordination polymers via the supercritical route was close to 100% because both the reactants were almost completely depleted in the performed experiments. © The Royal Society of Chemistry 2015.
Publisher version (URL)http://dx.doi.org/10.1039/c5dt00521c
Identifiersissn: 1477-9234
Appears in Collections:(ICMAB) Artículos
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