English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/137668
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Title

Exploring a novel preparation method of 1D metal organic frameworks based on supercritical CO2

AuthorsLópez Periago, Ana M. ; Vallcorba, Oriol ; Frontera, C.; Domingo, C.; Ayllón, José A.
Issue Date9-Mar-2015
PublisherRoyal Society of Chemistry (Great Britain)
CitationDalton Transactions 44: 7548-7553 (2015)
AbstractThe preparation of copper(II) one-dimensional MOFs using an eco-efficient method is reported here. This method is based exclusively on using supercritical CO<inf>2</inf> as a solvent, without the addition of any other additive or co-solvent. Neutral acetylacetonate copper complexes and two linear linkers, namely, the bidentate 4,4¿-bipyridine and 4,4¿-trimethylenedipyridine molecules, were reacted under compressed CO<inf>2</inf> at 60 °C and 20 MPa for periods of 4 or 24 h. The success achieved in the synthesis of the different studied 1D-MOFs was related to the solubility of the reagents in supercritical CO<inf>2</inf>. The reaction yield of the synthesized coordination polymers via the supercritical route was close to 100% because both the reactants were almost completely depleted in the performed experiments. © The Royal Society of Chemistry 2015.
Publisher version (URL)http://dx.doi.org/10.1039/c5dt00521c
URIhttp://hdl.handle.net/10261/137668
DOI10.1039/c5dt00521c
Identifiersissn: 1477-9234
Appears in Collections:(ICMAB) Artículos
Files in This Item:
File Description SizeFormat 
c5dt00521c.pdf1,21 MBAdobe PDFThumbnail
View/Open
Show full item record
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.