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Title

Ambiphilic allenes: synthesis and reactivity

AuthorsTejedor, David ; Méndez-Abt, Gabriela ; González-Platas, Javier; Ramírez, Miguel A.; García-Tellado, Fernando
Issue Date11-Mar-2009
PublisherRoyal Society of Chemistry
CitationChemical Communications (17): 2368-2370 (2009)
AbstractAmbiphilic allenes are generated by an organocatalyzed domino reaction of alkyl propiolates and aromatic 1,2-diketones; in the absence of any external chemical agent, these allenes perform a thermally-driven dimerization reaction to generate the corresponding fully-substituted cyclobutanes in a regio- and highly stereoselective manner.
Description3 pages, 1 figure, 2 tables, 3 schemes.-- PMID: 19377688 [PubMed].--Printed version published May 7, 2009.-- Supporting information available: Experimental section and physical data for compounds 4–9. CCDC 704023 and 704024.-- Available at: http://www.rsc.org/suppdata/CC/b8/b819613c/index.sht
Publisher version (URL)http://dx.doi.org/10.1039/b819613c
URIhttp://hdl.handle.net/10261/13702
DOI10.1039/b819613c
ISSN1359-7345
Appears in Collections:(IPNA) Artículos
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