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Título: | Corrosion mechanisms of mild steel in chloride-rich atmospheres |
Autor: | Fuente, Daniel de la CSIC ORCID; Díaz, Iván; Alcántara, J.; Chico, Belén; Simancas Peco, Joaquín CSIC; Llorente, Irene CSIC ORCID ; García Delgado, Antonio; Jiménez, José Antonio CSIC ORCID ; Adeva, Paloma CSIC ORCID CVN ; Morcillo, Manuel CSIC ORCID | Palabras clave: | Carbon steels Consolidated rust layer Corrosion |
Fecha de publicación: | 2016 | Editor: | John Wiley & Sons | Citación: | Materials and Corrosion - Werkstoffe und Korrosion 67(3): 227- 238 (2016) | Resumen: | This work analyses the corrosion mechanisms of carbon steel when exposed to marine atmospheres with very different chloride ion deposition rates. Two extreme situations are described, characterized by a >consolidated rust layer> (at relatively low atmospheric salinities), formed by a diffusion-controlled corrosion mechanism in which the reduction of dissolved oxygen in the aqueous film deposited on the metal is the predominant cathodic reaction, and an >exfoliated rust layer> (at high atmospheric salinities), where the cathodic reaction of hydrogen evolution becomes important, notably accelerating the corrosion process. The research has employed a range of near-surface and bulk sensitive analytical techniques (SEM/EDS, μXRD, and SEM/μRaman) to characterize the corrosion products and rust layers formed. | URI: | http://hdl.handle.net/10261/136521 | DOI: | 10.1002/maco.201508488 | Identificadores: | doi: 10.1002/maco.201508488 issn: 1521-4176 |
Aparece en las colecciones: | (CENIM) Artículos |
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