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dc.contributor.authorLovat, Giacomo-
dc.contributor.authorAbadia, Mikel-
dc.contributor.authorRogero, Celia-
dc.contributor.authorVittadini, Andrea-
dc.contributor.authorFloreano, Luca-
dc.date.accessioned2016-09-07T11:03:08Z-
dc.date.available2016-09-07T11:03:08Z-
dc.date.issued2015-
dc.identifierdoi: 10.1039/C5CP05437K-
dc.identifierissn: 1463-9076-
dc.identifiere-issn: 1463-9084-
dc.identifier.citationPhysical Chemistry Chemical Physics 17(44): 30119-30124 (2015)-
dc.identifier.urihttp://hdl.handle.net/10261/136458-
dc.description.abstractMetal-free porphyrin molecules adsorb on the rutile TiO(110) surface with their pyrrolic nitrogen atoms atop the O-bridge rows, whereas the iminic nitrogen atoms capture two additional hydrogen atoms. Hydrogenation occurs spontaneously at room temperature, irrespective of the distance of the polypyrrolic macrocycle from the surface, as varied by changing the porphyrin functionalization.-
dc.description.sponsorshipWe acknowledge support from the MIUR of Italy through PRIN project DESCARTES (no. 2010BNZ3F2), and by CINECA (ISCRA-B project E-TROPPO), from the Spanish Government (Grant MAT2013-46593-C6-4-P) and from the Basque Department of Education (Grant IT-621-13). M.A. is also grateful for financial support from DIPC.-
dc.publisherRoyal Society of Chemistry (UK)-
dc.relationMINECO/ICTI2013-2016/MAT2013-46593-C6-4-P-
dc.rightsclosedAccess-
dc.titleHydrogen capture by porphyrins at the TiO2(110) surface-
dc.typeartículo-
dc.identifier.doihttp://dx.doi.org/10.1039/C5CP05437K-
dc.date.updated2016-09-07T11:03:08Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderEusko Jaurlaritza-
dc.contributor.funderMinistero dell'Istruzione, dell'Università e della Ricerca-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.contributor.funderDonostia International Physics Center-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003407es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003086es_ES
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