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http://hdl.handle.net/10261/13546
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Boto, Alicia | - |
dc.contributor.author | Hernández, Dácil | - |
dc.contributor.author | Hernández, Rosendo | - |
dc.date.accessioned | 2009-06-09T08:00:06Z | - |
dc.date.available | 2009-06-09T08:00:06Z | - |
dc.date.issued | 2008-06-13 | - |
dc.identifier.citation | Journal of Organic Chemistry 73(14): 5287-5297 (2008) | en_US |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/10261/13546 | - |
dc.description | 11 pages, 2 figures, 2 tables, 7 schemes.-- PMID: 18549274 [PubMed].-- Printed version published Jul 18, 2008.-- Supporting information available: Preparation of substrate 22, including spectroscopic data of the synthetic intermediates and the final product. Procedures for the allylation and alkylation reactions, and spectroscopic data of phenyl ketones 20, 21, 27, butenolides 28-33 and 37-39, and cyclohexanones 46, 47, and 49. 1H and 13C NMR spectra for acetoxy acetal 24, allyl derivatives 18 and 19, phenyl ketones 20, 21, 26, and 27, butenolides 28-39, cyclohexanones 46-48 and 50-55, alkaloid analogues 56-61, and substrates 63-65 and 22.-- Available at: http://pubs.acs.org/doi/suppl/10.1021/jo800478a | en_US |
dc.description.abstract | Readily available sugar derivatives were transformed in a few steps into valuable, more complex products. The tandem radical scission of carbohydrates-oxidation reaction gave acetoxy acetals, which were converted into a variety of chiral C-alditols in good global yields and excellent 1,2-trans stereoselectivity. The reaction was the key step in the synthesis of hydroxylated gamma-substituted butenolides and bicyclic alkaloid analogues. | en_US |
dc.description.sponsorship | This work was supported by the Investigation Programmes PPQ2000-0728, PPQ2003-01379, and CTQ2006-14260/PPQ of the Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica, Ministerio de Educación y Ciencia and Ministerio de Ciencia y Tecnología, Spain. We also acknowledge financial support from FEDER funds. D.H. thanks the CSIC-Gobierno de Canarias, CSIC (I3P) and Ministerio de Educación y Ciencia (Plan Nacional FPU) for fellowships. | en_US |
dc.format.extent | 918459 bytes | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | closedAccess | en_US |
dc.title | Efficient conversion of carbohydrates into 1-C-alditols: application to the synthesis of chiral gamma-substituted butenolides and bicyclic alkaloid analogues | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1021/jo800478a | - |
dc.description.peerreviewed | Peer reviewed | en_US |
dc.relation.publisherversion | http://dx.doi.org/10.1021/jo800478a | en_US |
dc.contributor.funder | Comisión Interministerial de Ciencia y Tecnología, CICYT (España) | - |
dc.contributor.funder | Ministerio de Educación y Ciencia (España) | - |
dc.contributor.funder | Ministerio de Ciencia y Tecnología (España) | - |
dc.contributor.funder | European Commission | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.contributor.funder | Gobierno de Canarias | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100006280 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100007273 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
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