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Experimental setup for time-of-flight mass spectrometry ion detection in collisions of anionic species with neutral gas-phase molecular targets

AutorOller, J.C.; Ellis-Gibbings, L. ; Ferreira da Silva, F.; Limão-Vieira, P.; García, Gustavo
Fecha de publicación18-nov-2015
CitaciónInternational Workshop on Dissociative Electron Attachment (2015)
ResumenWe present a novel experimental setup for studying collision induced products resulting from the interaction of anionic beams with a neutral gas-phase molecular target [1]. The precursor projectile was admitted into vacuum through a commercial pulsed valve, with the anionic beam produced in a hollow cathode discharge-induced plasma, and guided to the interaction region by a set of deflecting plates where it was made to interact with the target beam. Depending on the collision energy regime, negative and positive species can be formed in the collision region and ions were time-of-flight (TOF) mass-analysed. Here, we present data on O2 precursor projectile, where we show clear evidence of O¿ and O2¿ formation from the hollow cathode source as well as preliminary results on the interaction of these anions with nitromethane, CH3NO2. The negative ions formed in such collisions were analysed using time-of-flight mass spectrometry. The five most dominant product anions were assigned to H¿, O¿, NO¿, CNO¿ and CH3NO2¿. The fragmentation pattern is significantly different from that obtained both in dissociative electron attachment and in alkali atom¿molecule collision experiments [2, 3]
Descripción2nd Meeting of the DEA Club, Mumbai, India, 18-20 Nov. 2015; https://indico.tifr.res.in/indico/conferenceDisplay.py?confId=4541
URIhttp://hdl.handle.net/10261/135466
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