English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/13499
COMPARTIR / IMPACTO:
Estadísticas
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Campo DC Valor Lengua/Idioma
dc.contributor.authorDíaz-Marrero, Ana R.-
dc.contributor.authorCueto, Mercedes-
dc.contributor.authorD'Croz, Luis-
dc.contributor.authorDarias, José-
dc.date.accessioned2009-06-06T23:45:56Z-
dc.date.available2009-06-06T23:45:56Z-
dc.date.issued2008-01-24-
dc.identifier.citationOrganic Letters 10(14): 3057-3060 (2008)en_US
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10261/13499-
dc.description4 pages, 5 figures.-- PMID: 18572945 [PubMed].-- Printed version published Jul 17, 2008.en_US
dc.descriptionSupporting information available at: http://pubs.acs.org/doi/suppl/10.1021/ol8010425-
dc.description.abstract1−3 isolated from Elysia diomedea are described. Compound 1 is an endoperoxide derivative of elysiapyrone A. The biomimetic-type transformation of compound 1 to elysiapyrone A catalyzed by neutral base transformed the endoperoxide to a vicinal diepoxide, thus suggesting the endoperoxide as a key intermediate in the biosynthesis of elysiapyrone A. A biogenetic pathway for their formation involving a cycloaddition of singlet oxygen to a polypropionate alkenyl open chain is proposed.en_US
dc.description.sponsorshipThis work was supported by the Ministerio de Educación y Ciencia (BIO2007-61745, SAF2006-03004) and DGUI Gobierno de Canarias (PIO42005, PUB2005/030). The STRI provided support and facilities for field work.-
dc.format.extent508124 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsclosedAccessen_US
dc.titleValidating an endoperoxide as a key intermediate in the biosynthesis of elysiapyronesen_US
dc.typeArtículoen_US
dc.identifier.doi10.1021/ol8010425-
dc.description.peerreviewedPeer revieweden_US
dc.relation.publisherversionhttp://dx.doi.org/10.1021/ol8010425en_US
dc.contributor.funderMinisterio de Educación y Ciencia (España)-
dc.contributor.funderGobierno de Canarias-
Aparece en las colecciones: (IPNA) Artículos
Ficheros en este ítem:
No hay ficheros asociados a este ítem.
Show simple item record
 

Artículos relacionados:


NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.