English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/13474
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Exportar a otros formatos:

Title

A convenient and chemoselective one-pot oxidation/Wittig reaction for the C2-homologation of carbohydrate-derived glycols

AuthorsPinacho Crisóstomo, Fernando R. ; Carrillo Fumero, Romen ; Martín, Tomás ; García-Tellado, Fernando ; Martín, Víctor S.
Issue Date22-Oct-2005
PublisherAmerican Chemical Society
CitationJournal of Organic Chemistry 70(24): 10099-10101 (2005)
AbstractA simple and convenient one-pot protocol for the chemoselective C2-homologation of carbohydrate-derived glycols is described. The method comprises the chemoselective oxidation of the glycol to the corresponding hydroxyaldehyde and the subsequent Wittig alkenylation. In addition, the method does not need selective protective group manipulation, and it is safe, economical, fast (5 to 6 h), and bench-friendly. Its general utility is discussed.
Description3 pages, 2 tables.-- PMID: 16292846 [PubMed].-- Printed version published Nov 25, 2005.
Supporting information available: Spectroscopic and analytical data for several compounds.-- Available at: http://pubs.acs.org/doi/suppl/10.1021/jo051566e
Erratum in: Journal of Organic Chemistry 71(3): 1288 (2006), doi: 10.1021/jo052606h.
Publisher version (URL)http://dx.doi.org/10.1021/jo051566e
URIhttp://hdl.handle.net/10261/13474
DOIhttp://dx.doi.org/10.1021/jo051566e
ISSN0022-3263
Appears in Collections:(IPNA) Artículos
Files in This Item:
File Description SizeFormat 
Convenient_and_Chemoselective-Garcia-Tellado.pdf130,65 kBAdobe PDFThumbnail
View/Open
corrigendum.pdf92,47 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.