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http://hdl.handle.net/10261/13459
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Boto, Alicia | en_US |
dc.contributor.author | Hernández, Rosendo | en_US |
dc.contributor.author | Montoya, Adriana | en_US |
dc.contributor.author | Suárez, Ernesto | - |
dc.date.accessioned | 2009-06-04T08:42:13Z | - |
dc.date.available | 2009-06-04T08:42:13Z | - |
dc.date.issued | 2004-01-14 | en_US |
dc.identifier.citation | Tetrahedron Letters 45(7): 1559-1563 (2004) | en_US |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.uri | http://hdl.handle.net/10261/13459 | - |
dc.description | 5 pages, 1 table, 6 schemes.-- Printed version published Feb 9, 2004. | - |
dc.description.abstract | The fragmentation of primary alkoxyl radicals, often described as low yielding and plagued by side reactions, proceeded in good to excellent yields when aminol derivatives were used as substrates. Remarkably, no side reactions such as hydrogen abstraction or oxidation were observed. The fragmentation can be coupled with an alkylation reaction to give 2-substituted pyrrolidine and piperidine rings such as alkaloid analogues and functionalized, chiral nitrogen heterocycles. | - |
dc.description.sponsorship | This work was supported by the Investigation Programme PPQ2000-0728 of the Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica, Dirección General de Investigación, Ministerio de Ciencia y Tecnología, Spain. We also acknowledge financial support from FEDER funds. A.M. thanks the C.S.I.C. (M.C.yT.) for an I3P fellowship. | - |
dc.format.extent | 2373 bytes | - |
dc.format.extent | 291947 bytes | - |
dc.format.mimetype | text/plain | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | - |
dc.rights | closedAccess | en_US |
dc.subject | Radicals | - |
dc.subject | Alkaloids | - |
dc.subject | Acyliminium ions | - |
dc.subject | Fragmentation | - |
dc.subject | Nucleophilic addition | - |
dc.subject | Nitrogen heterocycles | - |
dc.subject | Synthesis | - |
dc.title | Synthesis of alkaloids from aminol derivatives by β-fragmentation of primary alkoxyl radicals | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1016/j.tetlet.2003.12.003 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.tetlet.2003.12.003 | - |
dc.contributor.funder | Ministerio de Ciencia y Tecnología (España) | - |
dc.contributor.funder | European Commission | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100006280 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.languageiso639-1 | en | - |
item.fulltext | No Fulltext | - |
item.openairetype | artículo | - |
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