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Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/13458
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dc.contributor.authorCueto, Mercedesen_US
dc.contributor.authorD'Croz, Luisen_US
dc.contributor.authorMaté, Juan L.en_US
dc.contributor.authorSan Martín, Aurelioen_US
dc.contributor.authorDarias, Joséen_US
dc.date.accessioned2009-06-04T08:41:49Z-
dc.date.available2009-06-04T08:41:49Z-
dc.date.issued2005-01-13en_US
dc.identifier.citationOrganic Letters 7(3): 415-418 (2005)en_US
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10261/13458-
dc.description4 pages, 1 figure, 1 scheme.-- PMID: 15673253 [PubMed].-- Printed version published Feb 3, 2005.-
dc.descriptionSupporting information (Spectral data and experimental procedures) available at: http://pubs.acs.org/doi/suppl/10.1021/ol0477428-
dc.description.abstractBiogenetically interesting polypropionate-derived metabolites 1 and 2, featuring an unprecedented skeleton, have been isolated from the sea slug Elysia diomedea. Their enantiomeric character indicates that the current spontaneous electrocyclization cascade biogenetic hypothesis for the bicyclo[4.2.0]octane core must be enzymatically aided. These compounds are isomeric with the 15-nor-9,10-deoxytridachione/15-norphotodeoxytridachione pair of metabolites and encourage speculation about their biosynthetic relationship.-
dc.description.sponsorshipThis work was supported by the MEC (PPQ2002-02494) and the Canary Islands Government (PI2002/044). The STRI provided support and facilities. Dr. M. Gupta, Dr. J. A. Gómez, J. del Rosario, and D. Macías provided technical support. J. Maté received support from the U.S. NSF, Biological Oceanography Program (OCE- 9711529).-
dc.format.extent2373 bytes-
dc.format.extent86060 bytes-
dc.format.mimetypetext/plain-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherAmerican Chemical Society-
dc.rightsclosedAccessen_US
dc.titleElysiapyrones from Elysia diomedea. Do such metabolites evidence an enzymatically assisted electrocyclization cascade for the biosynthesis of their bicyclo[4.2.0]octane core?en_US
dc.typeartículoen_US
dc.identifier.doi10.1021/ol0477428-
dc.relation.publisherversionhttp://dx.doi.org/10.1021/ol0477428-
dc.contributor.funderMinisterio de Educación y Ciencia (España)-
dc.contributor.funderGobierno de Canarias-
dc.contributor.funderNational Science Foundation (US)-
dc.identifier.funderhttp://dx.doi.org/10.13039/100000001es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.languageiso639-1en-
item.fulltextNo Fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.grantfulltextnone-
item.openairetypeartículo-
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