English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/133634
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

DC FieldValueLanguage
dc.contributor.authorBlaszczyk-Lezak, Iwona-
dc.contributor.authorDesmaret, V.-
dc.contributor.authorMijangos, Carmen-
dc.date.accessioned2016-06-17T08:09:34Z-
dc.date.available2016-06-17T08:09:34Z-
dc.date.issued2016-
dc.identifierdoi: 10.3144/expresspolymlett.2016.24-
dc.identifierissn: 1788-618X-
dc.identifiere-issn: 1788-618X-
dc.identifier.citationExpress Polymer Letters 10: 259-272 (2016)-
dc.identifier.urihttp://hdl.handle.net/10261/133634-
dc.description.abstractIntrinsically or extrinsically conducting polymers are considered good candidates for replacement of metals in specific applications. In order to further expand their applications, it seems necessary to examine the influence of confinement effects on the electric properties of nanostructured conducting polymers in comparison to the bulk. The present study reports a novel way to fabricate and characterize high quality and controllable one-dimensional (1D) polymer nanostructures with promising electrical properties, with the aid of two examples polyaniline (PANI) and poly(vinylidene fluoride) with multiwall carbon nanotubes (PVDF-MWCNT) as representative of intrinsically and extrinsically conducting polymers, respectively. In this work, porous anodic aluminum oxide (AAO) templates have been used both as a nanoreactor to synthesize 1D PANI nanostructures by polymerization of the ANI monomer and as a nanomold to prepare 1D PVDFMWCNT nanorods by melt infiltration of the precursor PVDF-MWCNT film. The obtained polymer nanostructures were morphologically and chemically characterized by SEM and Confocal Raman Spectroscopy, respectively, and the electrical properties determined by Broadband Dielectric Spectroscopy (BDS) in a non-destructive way. SEM study allowed to establish the final nanostructure of PANI and PVDF-MWCNT and confirmed, in both cases, the well-aligned and uniform rodlike polymer nanostructures. Confocal Raman Microscopy has been performed to study the formation of the conducting emeraldine salt of PANI through all the length of AAO nanocavities. Finally, the electrical conductivity of both types of polymer nanostructures was easily evaluated by means of Dielectric Spectroscopy.-
dc.description.sponsorshipFinancial support from the Spanish ‘Ministerio de Economia y Competitividad’ under projects MAT2011-24797 and MAT2014-53437-C2-1 is acknowledged. The authors thank D. Gómez for SEM experiments and I. Muñoz for Raman spectra. Authors thank Miguel Ángel López Manchado por providing MWCNTs-
dc.publisherBudapest University of Technology-
dc.rightsclosedAccess-
dc.subjectConducting polymers-
dc.subjectBroadband dielectric spectroscopy-
dc.subjectAAO template-
dc.subjectNanocomposites-
dc.titleElectrically conducting polymer nanostructures confined in anodized aluminum oxide templates (AAO)-
dc.typeartículo-
dc.identifier.doi10.3144/expresspolymlett.2016.24-
dc.relation.publisherversionhttp://dx.doi.org/10.3144/expresspolymlett.2016.24-
dc.date.updated2016-06-17T08:09:35Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
Appears in Collections:(ICTP) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
View/Open
Show simple item record
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.