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dc.contributor.authorSouto Salom, Manueles_ES
dc.contributor.authorLloveras, Vegaes_ES
dc.contributor.authorVela, Sergies_ES
dc.contributor.authorFumanal, Mariaes_ES
dc.contributor.authorRatera, Immaculadaes_ES
dc.contributor.authorVeciana, Jaumees_ES
dc.date.accessioned2016-06-10T10:55:44Z-
dc.date.available2016-06-10T10:55:44Z-
dc.date.issued2016-06-
dc.identifier.citationJournal of Physical Chemistry Letters 7(12): 2234–2239 (2016)es_ES
dc.identifier.issn1948-7185-
dc.identifier.urihttp://hdl.handle.net/10261/133310-
dc.description.abstractThe diradical acceptor–donor–acceptor triad 1••, based on two polychlorotriphenylmethyl (PTM) radicals connected through a tetrathiafulvalene(TTF)–vinylene bridge, has been synthesized. The generation of the mixed-valence radical anion, 1•–, and triradical cation species, 1•••+, obtained upon electrochemical reduction and oxidation, respectively, was monitored by optical and ESR spectroscopy. Interestingly, the modification of electron delocalization and magnetic coupling was observed when the charged species were generated and the changes have been rationalized by theoretical calculations.es_ES
dc.description.sponsorshipThis work was supported by the DGI grant (CTQ2013-40480- R), the Networking Research Center on Bioengineering, Biomaterials, and Nanomedicine (CIBER-BBN), and the Generalitat de Catalunya (grant 2014-SGR-17). ICMAB acknowledges support from the Spanish Ministry of Economy and Competitiveness, through the “Severo Ochoa” Programme for Centres of Excellence in R&D (SEV-2015-0496). M.S. is enrolled in the Material Science Ph.D. program of UAB and is grateful to MEC for a FPU predoctoral grant. S.V. and M.F. are thankful to the LabEx-Chemistry of Complex Systems for postdoctoral grants (ANR-10-LABX-0026CSC) and to the regional High-Performance Computing (HPC) center in Strasbourg for computational resources. We thank Amable Bernabé for the MALDI spectroscopy.es_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relationMINECO/ICTI2013-2016/CTQ2013-40480-Res_ES
dc.relationMINECO/ICTI2013-2016/SEV-2015-0496-
dc.relation.isversionofPostprintes_ES
dc.rightsopenAccessen_EN
dc.titleThree Redox States of a Diradical Acceptor−Donor−Acceptor Triad: Gating the Magnetic Coupling and the Electron Delocalizationes_ES
dc.typeartículoes_ES
dc.identifier.doi10.1021/acs.jpclett.6b00912-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1021/acs.jpclett.6b00912es_ES
dc.embargo.terms2017-06-30es_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderCentro de Investigación Biomédica en Red Bioingeniería, Biomateriales y Nanomedicina (España)es_ES
dc.contributor.funderGeneralitat de Catalunyaes_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100005053es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100002809es_ES
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