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Título: | Conjugated Microporous Polymers Incorporating BODIPY Moieties as Light-Emitting Materials and Recyclable Visible-Light Photocatalysts |
Autor: | Liras, Marta CSIC ORCID CVN; Iglesias, Marta CSIC ORCID ; Sánchez, Félix CSIC ORCID | Fecha de publicación: | 2016 | Editor: | American Chemical Society | Citación: | Macromolecules 49: 1666-1673 (2016) | Resumen: | Here we report the design and synthesis of a new conjugated microporous polymer based on a BODIPY dye (CMPBDP) which has shown excellent luminescence properties and an efficient heterogeneous photocatalytic activity. CMPBDP shows high thermal stability and high surface area with microporous size and efficiently catalyzes the selective oxidation of thioanisole into the corresponding sulfoxide via singlet oxygen under visible light (up to 500 nm). The photocatalytic rate of the heterogeneous materials is 4-fold faster that the corresponding soluble (used as reference) under the same reaction conditions and can be reused several times. | Versión del editor: | http://dx.doi.org/10.1021/acs.macromol.5b02511 | URI: | http://hdl.handle.net/10261/133181 | DOI: | 10.1021/acs.macromol.5b02511 | Identificadores: | doi: 10.1021/acs.macromol.5b02511 issn: 0024-9297 e-issn: 1520-5835 |
Aparece en las colecciones: | (ICMM) Artículos (IQOG) Artículos |
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