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Title

A panchromatic modification of the light absorption spectra of metal–organic frameworks

AuthorsOtal, E.H.; Kim, M.L.; Calvo, Mauricio E. CSIC ORCID ; Karvonen, L.; Fabregas, I.O.; Sierra, C.A.; Hinestroza, J.P.
Issue Date2016
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications, 52:6665-6668 (2016)
AbstractThe optical absorption of UiO-66–NH2 MOF was red-shifted using a diazo-coupling reaction. The modifications performed with naphthols and aniline yielded reddish samples, and the modifications with diphenylaniline yielded dark violet ones. The photocatalytic activity of these modified MOFs was assessed for methylene blue degradation, showing a good performance relative to traditional TiO2. The degradation performance was found to correlate with the red shift of the absorption edge. These findings suggest potential applications of these materials in photocatalysis and in dye sensitized solar cells.
Publisher version (URL)http://dx.doi.org/10.1039/C6CC02319C
URIhttp://hdl.handle.net/10261/132905
DOI10.1039/C6CC02319C
Appears in Collections:(ICMS) Artículos




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