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Caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the Antarctic sponge Suberites caminatus

AuthorsDíaz-Marrero, Ana R. ; Brito, Inmaculada ; Dorta, Enrique ; Cueto, Mercedes ; San Martín, Aurelio; Darias, José
Issue Date4-Jul-2003
CitationTetrahedron Letters 44(31): 5939-5942 (2003)
AbstractA new sesterterpene, caminatal 1, containing a bicyclic terpenoid moiety with an aldehyde appendage in combination with an isolated isoprenic aromatic ring leading to a novel carbon skeleton has been obtained from the Antarctic sponge Suberites caminatus. Its structure and relative stereochemistry were established by spectroscopic evidence and biogenetic considerations.
The structure and relative stereochemistry of caminatal 1 are described.
Description4 pages, 2 figures, 1 table.-- Printed version published Jul 28, 2003.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4039(03)01426-6
Appears in Collections:(IPNA) Artículos
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