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Carijenone, a novel class of bicyclic prostanoid from the eastern Pacific octocoral Carijoa multiflora

AuthorsDorta, Enrique ; Díaz-Marrero, Ana R. ; Cueto, Mercedes ; D'Croz, Luis; Maté, Juan L.; Darias, José
Issue Date22-May-2004
PublisherAmerican Chemical Society
CitationOrganic Letters 6(13): 2229-2232 (2004)
AbstractAn unprecedented biogenetically interesting bicyclic prostanoid 1, carijenone, has been isolated from the eastern Pacific octocoral Carijoa multiflora. The C-12 oxygenated function, characteristic of the coral cyclopentanone fatty acid derivatives, is involved in the formation of a five-membered oxane ring fused to the cyclopentane network. Its structure and stereochemistry were determined on the basis of spectral studies and molecular mechanics calculations.
Description4 pages, 3 figures, 1 table.-- PMID: 15200327 [PubMed].-- Printed version published Jun 24, 2004.
Supporting Information Available: 1H and 13C NMR spectra of carijenone 1 and experimental procedure.-- Available at: http://pubs.acs.org/doi/suppl/10.1021/ol049287l
Publisher version (URL)http://dx.doi.org/10.1021/ol049287l
Appears in Collections:(IPNA) Artículos
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