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Title

Conformational analysis and absolute stereochemistry of 'spongian'-related metabolites

AuthorsDíaz-Marrero, Ana R. ; Dorta, Enrique ; Cueto, Mercedes ; San Martín, Aurelio; Darias, José
KeywordsSponges
Dendroceratida
Stereochemistries
Diterpenes
Issue Date26-Jan-2004
PublisherElsevier
CitationTetrahedron 60(5): 1073-1078 (2004)
AbstractNew degraded and rearranged diterpenoids, 5–8, have been isolated from the Antarctic sponge Dendrilla membranosa. The structure and relative stereochemistry of these compounds were determined by spectroscopic data. The absolute stereochemistry of 5 was determined by spectroscopic data using a chiral reagent. Conformational studies allowed us to assign also the absolute stereochemistry of 6–8, as well as those previously isolated spongian-derived metabolites with known relative stereochemistries.
Description6 pages, 1 figure, 2 tables, 1 scheme.-- Available online Dec 30, 2003.
Publisher version (URL)http://dx.doi.org/10.1016/j.tet.2003.11.077
URIhttp://hdl.handle.net/10261/13267
DOI10.1016/j.tet.2003.11.077
ISSN0040-4020
Appears in Collections:(IPNA) Artículos
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