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dc.contributor.authorDíaz-Marrero, Ana R.en_US
dc.contributor.authorCueto, Mercedesen_US
dc.contributor.authorDorta, Enriqueen_US
dc.contributor.authorRovirosa, Juanaen_US
dc.contributor.authorSan Martín, Aurelioen_US
dc.contributor.authorDarias, José-
dc.date.accessioned2009-05-26T13:27:15Z-
dc.date.available2009-05-26T13:27:15Z-
dc.date.issued2002-07-20en_US
dc.identifier.citationOrganic Letters 4(17): 2949-2952 (2002)en_US
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10261/13223-
dc.description4 pages, 2 figures, 2 tables, 1 scheme.-- PMID: 12182596 [PubMed].-- Printed version published Aug 22, 2002.-
dc.descriptionSupporting information available: Spectral data for compound 1 and a detailed experimental procedure.-- Available at: http://pubs.acs.org/doi/suppl/10.1021/ol026353f-
dc.description.abstractEmpirical rules based on 13C and 1H NMR spectroscopy to determine the regiochemistry and geometry of the 1,2-bromochloro vinyl portion of naturally occurring or synthetic compounds containing this functionality are proposed. The key feature of the method comes from the comparison of the spectral data of the new monoterpene metabolite, prefuroplocamioid, isolated from Plocamium cartilagineum, with those of other marine monoterpenes, as well as with some model compounds found in the literature.-
dc.description.sponsorshipThis work was supported by the Comisión Interministerial de Ciencia y Tecnología (CICYT), FEDER, Subdirección General de Cooperación Internacional, and the Cooperation Program between the Consejo Superior de Investigaciones Científicas (CSIC)-Universidad de Chile. A. R. D.-M. and E. D. acknowledge a fellowship from the CICYT.-
dc.format.extent2373 bytes-
dc.format.extent65356 bytes-
dc.format.mimetypetext/plain-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherAmerican Chemical Society-
dc.rightsclosedAccessen_US
dc.titleGeometry and halogen regiochemistry determination of vicinal vinyl dihalides by 1H and 13C NMR. Application to the structure elucidation of prefuroplocamioid, an unusual marine monoterpeneen_US
dc.typeartículoen_US
dc.identifier.doihttp://dx.doi.org/10.1021/ol026353f-
dc.relation.publisherversionhttp://dx.doi.org/10.1021/ol026353f-
dc.contributor.funderComisión Interministerial de Ciencia y Tecnología, CICYT (España)-
dc.contributor.funderEuropean Commission-
dc.contributor.funderUniversidad de Chile-
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)-
dc.contributor.funderMinisterio de Asuntos Exteriores y Cooperación (España)-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100007273es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100005853es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003767es_ES
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