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Electron bottleneck in the charge/discharge mechanism of lithium titanates for batteries

AutorVentosa, Edgar; Arbiol, Jordi; Morante, Joan Ramon
Fecha de publicación2015
EditorWiley-VCH
CitaciónChemSusChem 8(10): 1737-1744 (2015)
ResumenThe semi-solid flow battery (SSFB) is a promising storage energy technology featured by employing semi-solid fluid electrodes containing conductive additive and active Li-ion battery materials. The state of art anode material for SSFB is Li4Ti5O12 (LTO). This work shows that LTO improves drastically the performance in fluid electrode via hydrogen annealing manifesting the importance of the electrical conductivity of the active material in SSFBs. On the other hand, the properties of fluid electrodes allow the contributions of ionic and electrical resistance to be separated in operando. The asymmetric overpotential observed in Li4Ti5O12 and TiO2 is proposed to originate from the so-called electron bottleneck mechanism based on the transformation from electrically insulator to conductor upon (de-)lithiation, or vice versa, which should be considered when modelling, evaluating or designing advanced materials based on Li4Ti5O12, TiO2 or others with insulating-conducting behavior materials.
URIhttp://hdl.handle.net/10261/131662
DOI10.1002/cssc.201500349
Identificadoresdoi: 10.1002/cssc.201500349
e-issn: 1864-564X
issn: 1864-5631
Aparece en las colecciones: (CIN2) Artículos
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