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Title

Hydrophobic coating of mica by stearic acid vapor deposition

AuthorsSauthier, Guillaume ; Segura, Juan José ; Fraxedas, J. ; Verdaguer, Albert
KeywordsStearic acid
HydrophobiC
Atomic force microscopy
Self-assembled monolayer
Issue Date2014
PublisherElsevier
CitationColloids and Surfaces A: Physicochemical and Engineering Aspects 443: 331-337 (2014)
AbstractWe report on the preparation of thin films of stearic acid on mica by sublimation in air. We correlate their affinity to water (hydrophobic vs. hydrophilic character) to the morphology of the films as observed by Atomic Force Miscorcopy (AFM). Submonolayer and monolayer coverage exhibited hydrophilic character with dendritic shape defective self-assembled monolayer structures. With further exposure to stearic acid regular polyhedric multilayer three-dimensional structures formed on top of the monolayer, following the Stranski–Krastanov mechanism of growth. These structures were found to be compatible with a stearic acid bulk crystal structure. Coalesce of the structures generated a hydrophobic multilayer coating showing spiral growth. However, the multilayer coating was not homogeneous showing areas with only defective monolayer coating that still exposes bare mica.
URIhttp://hdl.handle.net/10261/131564
DOI10.1016/j.colsurfa.2013.11.031
Identifiersdoi: 10.1016/j.colsurfa.2013.11.031
issn: 0927-7757
Appears in Collections:(CIN2) Artículos
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