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Título: | Nanostructured p-type Cr/V2O5 thin films with boosted thermoelectric properties |
Autor: | Loureiro, Joana; Reparaz, J. S. CSIC ORCID; Alzina, Francesc CSIC ORCID; Sotomayor Torres, C. M. CSIC ORCID; Cuffe, John CSIC ORCID; Ferreira, Isabel | Fecha de publicación: | 2014 | Editor: | Royal Society of Chemistry (UK) | Citación: | Journal of Materials Chemistry A 2(18): 6456-6462 (2014) | Resumen: | The urgent need for non-toxic and abundant thermoelectric materials has become a significant motivation to improve the figures of merit of metal oxides in order to remove the barrier towards their widespread use for thermoelectric applications. Here we show the influence of a Cr layer in boosting the thermoelectric properties of vanadium pentoxide (V2O5) thin films, deposited by thermal evaporation and annealed at 500 °C. The Cr to V2O5 thickness ratio controls the morphological and thermoelectric properties of the thin films produced. The optimized Seebeck coefficient and power factor values at room temperature are +50 μV K−1 and 7.9 × 10−4 W m−1 K−2, respectively. The nanograin structure of the films is responsible for an improvement in the electrical conductivity up to 3 × 105 (Ω m)−1 with a typical thermal conductivity of 1.5 W m−1 K−1. These results combine to yield promising p-type thermoeletric CrV2O5 thin films with a ZT of 0.16 at room temperature. | URI: | http://hdl.handle.net/10261/131509 | DOI: | 10.1039/C3TA15168A | Identificadores: | doi: 10.1039/C3TA15168A issn: 2050-7488 e-issn: 2050-7496 |
Aparece en las colecciones: | (CIN2) Artículos |
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