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Title

Efficient multi-click approach to well-defined two-faced octasilsesquioxanes: the first perfect Janus nanocube

AuthorsBlázquez-Moraleja, Aberto; Pérez-Ojeda, M. Eugenia ; Suárez, José Ramón; Jimeno, M. Luisa ; Chiara, José Luis
Issue Date1-Mar-2016
PublisherRoyal Society of Chemistry
CitationChemCommun 52: 5792-5795 (2016)
AbstractThe preparation of the first structurally well-defined Janus nanocube showing two chemically distinct opposed faces is described. The synthetic approach is based on a highly efficient and symmetrycontrolled CuAAC functionalization of an octa-azido cubic silsesquioxane with a conformationally constrained tetra-alkyne with an appropriate spatial orientation of the triple bonds.
Publisher version (URL)http://dx.doi.org/10.1039/c6cc00896h
URIhttp://hdl.handle.net/10261/131380
DOI10.1039/c6cc00896h
ISSN1359-7345
E-ISSN1364-548X
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